Bithiophene imide bti
WebApr 14, 2024 · Development of high-performance unipolar n-type organic semiconductors still remains as a great challenge. In this work, all-acceptor bithiophene imide-based ladder-type small molecules BTIn and semiladder-type homopolymers PBTIn (n = 1–5) were synthesized, and their structure–property correlations were studied in depth. It was found …
Bithiophene imide bti
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WebFeb 9, 2011 · Bithiophene-imide-based polymeric semiconductors for field-effect transistors: synthesis, structure-property correlations, charge carrier polarity, and device stability ... to or slightly lower than current state-of-the-art p-type polymer semiconductors (0.1-0.6 cm(2) V(-1) s(-1)). Although BTI building block incorporation … WebJun 11, 2024 · Among various imide-functionalized (hetero)arenes, the bithiophene diimide (BTI) has been proven to be an excellent one. ... and A-A type polymers based on bithiophene imide or thiozothiophene imide have achieved excellent unipolar n-type transistors and ETLs in perovskite solar cells. 37 Developing effective polymerization …
WebBithiophene imide (BTI) is a promising building block for constructing n‐type organic semiconductors. The β‐positions of thiophene in BTI offer an exceptional opportunity for further ... WebOct 7, 2024 · To attenuate the steric hindrance associated with NDI and PDI, a novel imide-functionalized heteroarene, bithiophene imide (BTI), was designed; however, the BTI …
WebDriven by the exceptional success of 2,2′-bithiophene-3,3′-dicarboximide imide (BTI) for enabling high-performance polymer semiconductors, herein two BTI analogues 2,2′ … Webabstract = "A distannylated electron-deficient bithiophene imide (BTI-Tin) monomer was synthesized and polymerized with imide-functionalized co-units to afford homopolymer PBTI and copolymer P(BTI-BTI2), both featuring an acceptor–acceptor backbone with high molecular weight. Both polymers exhibited excellent unipolar n-type character in ...
WebDec 1, 2024 · Herein, by devising two new aldehyde-functionalized bithiophene imide (BTI)-type building blocks, we designed and synthesized two acceptor-acceptor type n-type polymers, BTI-BD and BTI2-BD, on the basis of an environmentally benign, transition metal-free and thus cost-effective aldol condensation.
WebAmong various electron-deficient building blocks, bithiophene imide (BTI), as an imide-functionalized arene, has been proved as a prominent one for constructing n-type polymer semiconductors. 6 The β-positions of thiophenes in BTI afford an unprecedented opportunity for structural optimization via backbone expansion and core modification. how do you use a mobile phoneWebDec 15, 2024 · Two new bithiophene imide (BTI)-based polymer donors were designed and synthesized. Fine-tuning the aggregation and orientation of BTI-based polymer donors was achieved by incorporating the linear n-octyl group into thiophene π-bridge. G15 showed excellent compatibility with non-fullerene electron acceptors. The G15-based organic … phonicsplay phase 4WebNov 27, 2024 · Two new bithiophene imide (BTI)-based n-type polymers were synthesized. f-BTI2-FT based on a fused BTI dimer showed a smaller band gap, a lower LUMO, and higher crystallinity than s-BTI2-FT containing a BTI dimer connected through a single bond. s-BTI2-FT exhibited a remarkable electron mobility of 0.82 cm 2 V-1 s-1, and f-BTI2-FT … phonicsplay phaseWebApr 15, 2005 · Theoretical design of high-mobility bithiophene imide (BTI) derivative polymeric semiconductors Berkay Sütay , G. Onaran , E. Yıldırım , M. Yurtsever Materials Science, Chemistry phonicsplay ighWebA distannylated electron-deficient bithiophene imide (BTI-Tin) monomer was synthesized and polymerized with imide-functionalized co-units to … phonicsplay phase 6WebOct 10, 2024 · Abstract. Two new bithiophene imide (BTI)-based n-type polymers were synthesized. f-BTI2-FT based on a fused BTI dimer showed a smaller band gap, a lower … phonicsplay planningWebImide-functionalized arenes are highly promising π-conjugated materials. 8,26 The bithiophene imide (BTI) was first synthesized as an electron-deficient unit by Marks et al., 27 and its incorporation into polymers … phonicsplay phase 5 games